FA4Pb2I7.5(SCN)0.5: n = 3 Member of Perovskite Homologous Series FAn+1Pbn\u22121I3n\u22121.5(SCN)0.5 with Columnar Defects<\/p>\n
Takuya Ohmi, James R. Neilson, Wataru Taniguchi, Tomoya Fukui, Teppei Nagase, Yuki Haruta, Makhsud I. Saidaminov, Takanori Fukushima, Masaki Azuma, Takafumi Yamamoto<\/p>\n
Hybrid organic\u2013inorganic halide perovskites are an emerging class of optoelectronic materials. Among them, there are many homologous series of Ruddlesden\u2013Popper and Dion\u2013Jacobson layered perovskites reported, but a homologous series based on defect ordering has not yet been discovered. Here, by using thiocyanate anion as a defect generator, we successfully synthesized a new defect-ordered perovskite FA4<\/sub>Pb2<\/sub>I7.5<\/sub>(SCN)0.5<\/sub> together with the previously reported FA6<\/sub>Pb4<\/sub>I13.5<\/sub>(SCN)0.5<\/sub>. These compounds can be represented respectively as n<\/i> = 3 and n<\/i> = 5 members of the perovskite homologous series FAn<\/i>+1<\/sub>Pbn<\/i>\u22121<\/sub>I3n<\/i>\u22121.5<\/sub>(SCN)0.5<\/sub> with ordered columnar defects, which is the first homologous series of defect-ordered hybrid perovskites. The optical band gap increases with an increase in the ordered defects in the lattice. FA4<\/sub>Pb2<\/sub>I7.5<\/sub>(SCN)0.5<\/sub> (n<\/i> = 3) exhibits photoluminescence emission, which is a feature of layered perovskites with a quantum-well structure. This study provides a new strategy to control the defect orderings for tuning their optical properties by incorporating thiocyanate.<\/p>\n FA4Pb2I7.5(SCN)0.5: n = 3 Member of Perovskite Homologous Series FAn+1Pbn\u22121I3n\u22121.5(SCN)0.5 with Columnar Defects Takuya Ohmi, James R. Neilson, Wataru Taniguchi, Tomoya Fukui, Teppei Nagase, Yuki Haruta, Makhsud I. Saidaminov, Takanori Fukushima, Masaki Azuma, Takafumi Yamamoto Hybrid organic\u2013inorganic halide perovskites are an emerging class of optoelectronic materials. Among them, there are many homologous series of Ruddlesden\u2013Popper […]<\/p>\n","protected":false},"author":222414606,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"advanced_seo_description":"","jetpack_seo_html_title":"","jetpack_seo_noindex":false,"_themeisle_gutenberg_block_has_review":false,"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_locale":"en_US","_original_post":"https:\/\/supraceramics.jp\/?p=1001","_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2}},"categories":[124830],"tags":[],"class_list":["post-1855","post","type-post","status-publish","format-standard","hentry","category-news","en-US"],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"","jetpack_likes_enabled":true,"jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/pe2JgX-tV","jetpack-related-posts":[{"id":1001,"url":"https:\/\/supraceramics.jp\/2024\/04\/1001\/","url_meta":{"origin":1855,"position":0},"title":"Publication | ACS Mater. Lett. (Ohmi, Fukui, Yamamoto et al.) \u201cFA4Pb2I7.5(SCN)0.5: n = 3 Member of Perovskite Homologous Series FAn+1Pbn\u22121I3n\u22121.5(SCN)0.5 with Columnar Defects\u201d","author":"shorike","date":"2024\u5e744\u670820\u65e5","format":false,"excerpt":"\u5171\u540c\u7814\u7a76\u6210\u679c\uff1a\u6b20\u9665\u3092\u4e26\u3079\u308b\u3053\u3068\u3067\u6709\u6a5f-\u7121\u6a5f\u30cf\u30a4\u30d6\u30ea\u30c3\u30c9\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u5316\u5408\u7269\u306e\u65b0\u305f\u306a\u6d3e\u751f\u69cb\u9020\u3092\u767a\u898b\uff08C01\u5c71\u672c, A03\u798f\u4e95\u3089\uff09 FA4Pb2I7.5(SCN)0.5: n = 3 Member of Perovskite Homologous Series FAn+1Pbn\u22121I3n\u22121.5(SCN)0.5 with Columnar Defects Takuya Ohmi, James R. Neilson, Wataru Taniguchi, Tomoya Fukui, Teppei Nagase, Yuki Haruta, Makhsud I. Saidaminov, Takanori Fukushima, Masaki Azuma, Takafumi Yamamoto FAPbI3(FA = CH(NH2)2)\u306a\u3069\u306e\u6709\u6a5f-\u7121\u6a5f\u30cf\u30a4\u30d6\u30ea\u30c3\u30c9\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u5316\u5408\u7269\u306f\u3001\u592a\u967d\u96fb\u6c60\u3001\u86cd\u5149\u4f53\u306a\u3069\u3055\u307e\u3056\u307e\u306a\u5206\u91ce\u3067\u5fdc\u7528\u304c\u671f\u5f85\u3055\u308c\u3066\u3044\u308b\u534a\u5c0e\u4f53\u6750\u6599\u3067\u3042\u308b\u3002\u672c\u7814\u7a76\u3067\u306f\u3001\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8FAPbI3\u306e\u30e8\u30a6\u5316\u7269\u30a4\u30aa\u30f3\uff08I\u2212\uff09\u306e\u4e00\u90e8\u3092\u5206\u5b50\u6027\u306e\u30a4\u30aa\u30f3\u3067\u3042\u308b\u30c1\u30aa\u30b7\u30a2\u30f3\u9178\u30a4\u30aa\u30f3\uff08SCN\u2212\uff09\u306b\u7f6e\u304d\u63db\u3048\u308b\u3053\u3068\u3067\u3001\u67f1\u72b6\u6b20\u9665\u304c\u6574\u5217\u3057\u305f\u65b0\u898f\u5316\u5408\u7269FA4Pb2I7.5(SCN)0.5\u306e\u5408\u6210\u306b\u6210\u529f\u3057\u305f\u3002\u3053\u306e\u5316\u5408\u7269\u306f\u3001\u540c\u30b0\u30eb\u30fc\u30d7\u304c\u904e\u53bb\u306b\u5831\u544a\u3057\u305f\u67f1\u72b6\u6b20\u9665\u3092\u6301\u3064FA6Pb4I13.5(SCN)0.5\u3068\u5408\u308f\u305b\u3066\u3001\u6b20\u9665\u91cf\u306b\u5bfe\u5fdc\u3059\u308b1\/n\uff08n\u306f\u6574\u6570\uff09\u3092\u4f7f\u3063\u3066FAn+1Pbn\u22121I3n\u22121.5(SCN)0.5\u3068\u3057\u3066\u7cfb\u7d71\u7684\u306b\u8a18\u8ff0\u3067\u304d\u308b\u3002\u3055\u3089\u306b\u3001n\u306e\u5024\u3092\u5909\u3048\u308b\u3053\u3068\u3067\u5149\u5b66\u7279\u6027\u304c\u5236\u5fa1\u3067\u304d\u308b\u3002\u6709\u6a5f-\u7121\u6a5f\u30cf\u30a4\u30d6\u30ea\u30c3\u30c9\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u306b\u304a\u3044\u3066\u3001\u6b20\u9665\u306e\u6574\u5217\u306b\u57fa\u3065\u304f\u5316\u5408\u7269\u7cfb\u5217\u304c\u793a\u3055\u308c\u305f\u4f8b\u306f\u3053\u308c\u307e\u3067\u306a\u304f\u3001\u3053\u306e\u6cd5\u5247\u306b\u57fa\u3065\u3044\u305f\u3055\u3089\u306a\u308b\u65b0\u898f\u7269\u8cea\u306e\u767a\u898b\u304c\u671f\u5f85\u3055\u308c\u308b\u3002 \u6771\u5de5\u5927\u30d7\u30ec\u30b9\u30ea\u30ea\u30fc\u30b9 ACS Materials Letter, 6, 1913\u20131919, (2024). (DOI: 10.1021\/acsmaterialslett.3c01514) https:\/\/pubs.acs.org\/doi\/10.1021\/acsmaterialslett.3c01514","rel":"","context":"In "News"","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2280,"url":"https:\/\/supraceramics.jp\/en\/2026\/01\/2280\/","url_meta":{"origin":1855,"position":1},"title":"Publication | J. Am. Chem. Soc. (Ohmi, Taniguchi, Bhawna, Fukui, Yamamoto et al.) \u201cDimensionality Reduction of Formamidinium-Rich Lead Iodide Perovskite-Derived Structures\u201d","author":"shorike","date":"2026\u5e741\u670819\u65e5","format":false,"excerpt":"Dimensionality Reduction of Formamidinium-Rich Lead Iodide Perovskite-Derived Structures Takuya Ohmi, Wataru Taniguchi, Bhawna, Tomoya Fukui, Yuki Haruta, Takayuki Nakanishi, Takanori Fukushima, Makhsud I. Saidaminov, Masaki Azuma, Takafumi Yamamoto* Formamidinium lead iodide, FAPbI3 (FA+ = CH(NH2)2+), with a cubic perovskite structure is among the most studied organic\u2013inorganic hybrid perovskites. Despite several\u2026","rel":"","context":"In "News"","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":698,"url":"https:\/\/supraceramics.jp\/2023\/09\/698\/","url_meta":{"origin":1855,"position":2},"title":"Publication | J. Am. Chem. Soc. (Ohmi, Maeda, Fujii, Yamamoto, et al.) \u201cThiocyanate-Stabilized Pseudo-cubic Perovskite CH(NH2)2PbI3 from Coincident Columnar Defect Lattices\u201d","author":"shorike","date":"2023\u5e749\u67082\u65e5","format":false,"excerpt":"\u5171\u540c\u7814\u7a76\u6210\u679c: \u5b89\u5b9a\u5316\u3055\u308c\u308b\u64ec\u7acb\u65b9\u6676\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8CH(NH2)2PbI3\u306b\u304a\u3051\u308b\u67f1\u72b6\u6b20\u9665\u683c\u5b50\u306e\u5f62\u6210\uff08C01\u5c71\u672c, C02\u524d\u7530, B03\u85e4\u4e95\u3089\uff09 Thiocyanate-Stabilized Pseudo-cubic Perovskite CH(NH2)2PbI3 from Coincident Columnar Defect Lattices Takuya Ohmi, Iain W. H. Oswald, James R. Neilson, Nikolaj Roth, Shunta Nishioka, Kazuhiko Maeda, Kotaro Fujii, Masatomo Yashima, Masaki Azuma, Takafumi Yamamoto \u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u592a\u967d\u96fb\u6c60\u306f\u3001\u4f4e\u30b3\u30b9\u30c8\u3067\u30d5\u30ec\u30ad\u30b7\u30d6\u30eb\u306a\u6b21\u4e16\u4ee3\u306e\u592a\u967d\u96fb\u6c60\u3068\u3057\u3066\u671f\u5f85\u3055\u308c\u3066\u304a\u308a\u3001\u518d\u751f\u53ef\u80fd\u30a8\u30cd\u30eb\u30ae\u30fc\u666e\u53ca\u306e\u4e00\u7aef\u3092\u62c5\u3046\u3002\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u69cb\u9020\u3092\u6301\u3064FAPbI3\u306f\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u592a\u967d\u96fb\u6c60\u306e\u4e3b\u8981\u306a\u6750\u6599\u3068\u3057\u3066\u77e5\u3089\u308c\u3066\u3044\u308b\u304c\u3001\u69cb\u9020\u306e\u5b89\u5b9a\u5316\u306b150\u2103\u4ee5\u4e0a\u306e\u9ad8\u6e29\u304c\u5fc5\u8981\u3067\u3042\u308a\u3001\u5ba4\u6e29\u3067\u306f\u5f90\u3005\u306b\u767a\u96fb\u52b9\u7387\u306e\u60aa\u3044\u5225\u306e\u69cb\u9020\u306b\u5909\u5316\u3057\u3066\u3057\u307e\u3046\u305f\u3081\u3001\u8010\u4e45\u6027\u306e\u5411\u4e0a\u304c\u8ab2\u984c\u3068\u3055\u308c\u3066\u3044\u305f\u3002\u672c\u7814\u7a76\u3067\u306f\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8FAPbI3\u306e\u30e8\u30a6\u5316\u7269\u30a4\u30aa\u30f3\uff08I-\uff09\u306e\u4e00\u90e8\u3092\u30c1\u30aa\u30b7\u30a2\u30f3\u9178\u30a4\u30aa\u30f3\uff08SCN-\uff09\u3067\u7f6e\u304d\u63db\u3048\u305f\u3001\u65b0\u3057\u3044\u6709\u6a5f\u2212\u7121\u6a5f\u30cf\u30a4\u30d6\u30ea\u30c3\u30c9\u5316\u5408\u7269\u306e\u5408\u6210\u306b\u521d\u3081\u3066\u6210\u529f\u3057\u305f\u3002\u7d50\u6676\u69cb\u9020\u89e3\u6790\u306e\u7d50\u679c\u3001\u672c\u5316\u5408\u7269\u306f\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u69cb\u9020\u306b\u4e00\u6b21\u5143\u306e\u6b20\u9665\u304c\u5468\u671f\u7684\u306b\u6574\u5217\u3057\u305f\u7279\u7570\u306a\u7d50\u6676\u69cb\u9020\u3092\u6301\u3064\u3053\u3068\u304c\u660e\u3089\u304b\u3068\u306a\u3063\u305f\u3002\u3055\u3089\u306b\u3001\u4eca\u56de\u5408\u6210\u306b\u6210\u529f\u3057\u305f\u5316\u5408\u7269\u306fFAPbI3\u3068\u5171\u5b58\u3059\u308b\u3053\u3068\u3067\u3001\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u69cb\u9020\u306e\u4f4e\u6e29\u3067\u306e\u5b89\u5b9a\u5316\u3092\u88dc\u52a9\u3059\u308b\u52b9\u679c\u304c\u3042\u308b\u3053\u3068\u304c\u660e\u3089\u304b\u3068\u306a\u3063\u305f\u3002\u3053\u306e\u77e5\u898b\u3092\u6d3b\u304b\u3059\u3053\u3068\u3067\u3001\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u592a\u967d\u96fb\u6c60\u306e\u8010\u4e45\u6027\u5411\u4e0a\u304c\u671f\u5f85\u3067\u304d\u308b\u3002 \u6771\u5de5\u5927\u30d7\u30ec\u30b9\u30ea\u30ea\u30fc\u30b9 https:\/\/www.titech.ac.jp\/news\/2023\/067395 Journal of American Chemical Society, in press (DOI: 10.1021\/jacs.3c05390) https:\/\/pubs.acs.org\/doi\/full\/10.1021\/jacs.3c05390","rel":"","context":"In "News"","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2278,"url":"https:\/\/supraceramics.jp\/2026\/01\/2278\/","url_meta":{"origin":1855,"position":3},"title":"Publication | J. Am. Chem. Soc. (Ohmi, Taniguchi, Bhawna, Fukui, Yamamoto et al.) \u201cDimensionality Reduction of Formamidinium-Rich Lead Iodide Perovskite-Derived Structures\u201d","author":"shorike","date":"2026\u5e741\u670819\u65e5","format":false,"excerpt":"Dimensionality Reduction of Formamidinium-Rich Lead Iodide Perovskite-Derived Structures Takuya Ohmi, Wataru Taniguchi, Bhawna, Tomoya Fukui, Yuki Haruta, Takayuki Nakanishi, Takanori Fukushima, Makhsud I. Saidaminov, Masaki Azuma, Takafumi Yamamoto* \u6709\u6a5f-\u7121\u6a5f\u30cf\u30a4\u30d6\u30ea\u30c3\u30c9\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u5316\u5408\u7269\u306f\u3001\u592a\u967d\u96fb\u6c60\u3001\u86cd\u5149\u4f53\u306a\u3069\u3055\u307e\u3056\u307e\u306a\u5206\u91ce\u3067\u5fdc\u7528\u304c\u671f\u5f85\u3055\u308c\u3066\u3044\u308b\u534a\u5c0e\u4f53\u6750\u6599\u3067\u3001\u4e16\u754c\u4e2d\u3067\u76db\u3093\u306b\u7814\u7a76\u3055\u308c\u3066\u3044\u307e\u3059\u3002\u672c\u7814\u7a76\u3067\u306f\u3001\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u592a\u967d\u96fb\u6c60\u7814\u7a76\u3067\u6700\u3082\u6709\u540d\u306a\u7d44\u6210\u306e\u4e00\u3064\u3067\u3042\u308bFA-Pb-I\u306e\u7d44\u307f\u5408\u308f\u305b\u306b\u304a\u3044\u3066\uff08FA\uff1aCH(NH2)2\u3001Pb:\u925b\u3001I:\u30e8\u30a6\u7d20\uff09\u3001\u65b0\u898f\u306e\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u69cb\u9020\u7cfb\u5217\u304c\u3042\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3057\u307e\u3057\u305f\u3002\u65b0\u898f\u306e\u7269\u8cea\u3068\u3057\u3066\u4eca\u5f8c\u306e\u7269\u6027\u958b\u62d3\u304c\u671f\u5f85\u3055\u308c\u308b\u3068\u3068\u3082\u306b\u3001\u3053\u308c\u307e\u3067\u30c7\u30d0\u30a4\u30b9\u306e\u6750\u6599\u3068\u3057\u3066\u4f7f\u308f\u308c\u3066\u304d\u305fFA-Pb-I\u7cfb\u306b\u4eca\u56de\u5831\u544a\u3057\u305f\u69cb\u9020\u304c\u542b\u307e\u308c\u3066\u3044\u308b\u53ef\u80fd\u6027\u3082\u9ad8\u304f\u3001\u6750\u6599\u306e\u89e3\u6790\u306b\u304a\u3044\u3066\u91cd\u8981\u306a\u77e5\u898b\u3068\u306a\u308a\u3048\u307e\u3059\u3002\u672c\u6210\u679c\u306f\u3001J. Am. Chem. Soc. \u8a8c\u306b\u30aa\u30f3\u30e9\u30a4\u30f3\u63b2\u8f09\u3055\u308c\u307e\u3057\u305f\u3002 J. Am. Chem. Soc. 2026, in press.","rel":"","context":"In "News"","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2067,"url":"https:\/\/supraceramics.jp\/en\/2025\/06\/2067\/","url_meta":{"origin":1855,"position":4},"title":"Publication | Inorg. Chem. (Ohmi, Ogawa, Yamamoto, et al.) \u201cGeometric Isomers of Bipyridinium in Lead Halide Perovskitoids\u201d","author":"shorike","date":"2025\u5e746\u670816\u65e5","format":false,"excerpt":"Geometric Isomers of Bipyridinium in Lead Halide Perovskitoids Takuya Ohmi, Soumya Kundu, Hanyang Ye, Wen Zhou, Kanta Ogawa, Yuki Haruta, Alejandra M. Navarrete-L\u00f3pez, Takafumi Yamamoto*, Makhsud I. Saidaminov* Organic\u2013inorganic hybrid lead halides are explored enthusiastically in light of the versatility of their crystal structures. Here, we report lead halide crystals\u2026","rel":"","context":"In "News"","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":1216,"url":"https:\/\/supraceramics.jp\/2022\/12\/1216\/","url_meta":{"origin":1855,"position":5},"title":"The 1st Symposium on Materials Chemistry for New Properties and Functions","author":"shorike","date":"2022\u5e7412\u670811\u65e5","format":false,"excerpt":"The 2nd Symposium on Materials Chemistry for New Properties and Functions Ookayama Main building 3F Room 345 (\u7b2c2 \u4f1a\u8b70\u5ba4), Tokyo Institute of Technology 5 December, 2022 Program: 9:30 Opening (Kazuhiko Maeda, Tokyo Tech) 9:35 Development of Sustainable and Safe Synthesis Method of Metal Oxynitrides Using Solid-Nitriding Agents (Kiyofumi Katagiri, Hiroshima\u2026","rel":"","context":"In "Event"","block_context":{"text":"Event","link":"https:\/\/supraceramics.jp\/en\/category\/event\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]}],"_links":{"self":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts\/1855","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/users\/222414606"}],"replies":[{"embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/comments?post=1855"}],"version-history":[{"count":1,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts\/1855\/revisions"}],"predecessor-version":[{"id":1857,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts\/1855\/revisions\/1857"}],"wp:attachment":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/media?parent=1855"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/categories?post=1855"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/tags?post=1855"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
\nPress release
\n<\/a>
\n
\nACS Materials Letter<\/em>, 6, 1913\u20131919, (2024). (DOI: 10.1021\/acsmaterialslett.3c01514)
\nhttps:\/\/pubs.acs.org\/doi\/10.1021\/acsmaterialslett.3c01514
\n<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"