Angewandte Chemie International Edition<\/em>, 2023, e20230946. DOI: 10.1002\/anie.202309469
\n<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"A Cationic Metal Glue Strategy for Expanding Paramagnetic Hetero-Multinuclear Metal\u2013Oxo Clusters within Polyoxometalate Ligands Takuo Minato, Masahiro Sadakane Precise structural design of large hetero-multinuclear metal-oxo clusters is crucial for controlling their large spin ground states and multielectron redox properties for application as a single-molecule magnet (SMM), molecular magnetic refrigeration, and efficient redox catalyst. However, it […]<\/p>\n","protected":false},"author":222414606,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"advanced_seo_description":"","jetpack_seo_html_title":"","jetpack_seo_noindex":false,"_themeisle_gutenberg_block_has_review":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_locale":"en_US","_original_post":"https:\/\/supraceramics.jp\/?p=660","_jetpack_feature_clip_id":0,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2},"jetpack_post_was_ever_published":false},"categories":[124830],"tags":[],"class_list":["post-1886","post","type-post","status-publish","format-standard","hentry","category-news","en-US"],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"","jetpack_likes_enabled":true,"jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/pe2JgX-uq","jetpack-related-posts":[{"id":660,"url":"https:\/\/supraceramics.jp\/2023\/07\/660\/","url_meta":{"origin":1886,"position":0},"title":"Publication | Angew. Chem. Int. Ed. (Minato, Sadakane) \u201cA Cationic Metal Glue Strategy for Expanding Paramagnetic Hetero-Multinuclear Metal\u2013Oxo Clusters within Polyoxometalate Ligands\u201d","author":"shorike","date":"2023\u5e747\u670829\u65e5","format":false,"excerpt":"\u5171\u540c\u7814\u7a76\u6210\u679c\uff1a\u30dd\u30ea\u30aa\u30ad\u30bd\u30e1\u30bf\u30ec\u30fc\u30c8\u914d\u4f4d\u5b50\u3092\u7528\u3044\u305f\"\u91d1\u5c5e\u30ab\u30c1\u30aa\u30f3\u63a5\u7740\u5264\u6226\u7565\"\u306b\u3088\u308b\u5e38\u78c1\u6027\u7570\u7a2e\u91d1\u5c5e\u591a\u6838\u69cb\u9020\u306e\u62e1\u5f35\uff08A02\u5b9a\u91d1\u3089\uff09 A Cationic Metal Glue Strategy for Expanding Paramagnetic Hetero-Multinuclear Metal\u2013Oxo Clusters within Polyoxometalate Ligands Takuo Minato, Masahiro Sadakane \u5927\u304d\u306a\u7570\u7a2e\u91d1\u5c5e\u591a\u6838\u69cb\u9020\u3092\u7cbe\u5bc6\u306b\u69cb\u9020\u8a2d\u8a08\u3059\u308b\u3053\u3068\u306f\u3001\u5927\u304d\u306a\u57fa\u5e95\u30b9\u30d4\u30f3\u3084\u591a\u96fb\u5b50\u9178\u5316\u9084\u5143\u7279\u6027\u3092\u5236\u5fa1\u3057\u3001\u5358\u5206\u5b50\u78c1\u77f3 (SMM)\u3001\u5206\u5b50\u78c1\u6c17\u51b7\u5a92\u3001\u52b9\u7387\u7684\u306a\u9178\u5316\u9084\u5143\u89e6\u5a92\u3068\u3057\u3066\u5fdc\u7528\u3059\u308b\u305f\u3081\u306b\u91cd\u8981\u3067\u3042\u308b\u3002\u3057\u304b\u3057\u3001\u5f93\u6765\u578b\u306e\u91d1\u5c5e\u30ab\u30c1\u30aa\u30f3\u3068\u914d\u4f4d\u5b50\u306e\u4e00\u6bb5\u968e\u7e2e\u5408\u53cd\u5fdc\u3092\u7528\u3044\u305f\u5834\u5408\u3001\u6700\u7d42\u751f\u6210\u7269\u306e\u69cb\u9020\u4e88\u6e2c\u306f\u56f0\u96e3\u3067\u3042\u3063\u305f\u3002\u672c\u7814\u7a76\u3067\u306f\u6b20\u640d\u578b\u30dd\u30ea\u30aa\u30ad\u30bd\u30e1\u30bf\u30ec\u30fc\u30c8 (POM)\u3092\u525b\u76f4\u306a\u7121\u6a5f\u591a\u5ea7\u914d\u4f4d\u5b50\u3068\u3057\u3066\u4f7f\u7528\u3057\u3001\u7570\u7a2e\u91d1\u5c5e\u591a\u6838\u69cb\u9020\u306e\u30b5\u30a4\u30ba\u3068\u6838\u6570\u3092\u62e1\u5f35\u3055\u305b\u308b\u300c\u91d1\u5c5e\u30ab\u30c1\u30aa\u30f3\u63a5\u7740\u5264\u6226\u7565\u300d\u306e\u63d0\u6848\u3068\u5b9f\u8a3c\u3092\u884c\u3063\u305f\u3002\u672c\u624b\u6cd5\u306b\u3088\u308a\u3001\u3053\u308c\u307e\u3067\u306b\u5831\u544a\u3055\u308c\u305fPOM\u306b\u304a\u3044\u3066\u6700\u5927\u306e\u5e38\u78c1\u6027\u7570\u7a2e\u91d1\u5c5e\u591a\u6838\u69cb\u9020\u3067\u3042\u308b{(FeMn4)Mn2Ln2(FeMn4)} (Ln = Gd, Tb, Dy, Lu)\u306e\u5408\u6210\u3068SMM\u7279\u6027\u306e\u5236\u5fa1\u306b\u6210\u529f\u3057\u305f\u3002\u3053\u308c\u3089\u306e\u69cb\u9020\u306f\u3001Mn\u304a\u3088\u3073Ln\u30ab\u30c1\u30aa\u30f3\u3092\u63a5\u7740\u5264\u3068\u3057\u3066\u3001{FeMn4}\u540c\u58eb\u3092\u7e4b\u3052\u308b\u3053\u3068\u306b\u3088\u308b\u4e88\u6e2c\u53ef\u80fd\u306a\u65b9\u6cd5\u3067\u5408\u6210\u3067\u304d\u305f\u3053\u3068\u304b\u3089\u3001\u300c\u91d1\u5c5e\u30ab\u30c1\u30aa\u30f3\u63a5\u7740\u5264\u6226\u7565\u300d\u306f\u3055\u3089\u306b\u5927\u304d\u306a\u7570\u7a2e\u91d1\u5c5e\u591a\u6838\u69cb\u9020\u3092\u539f\u5b50\u30ec\u30d9\u30eb\u3067\u6b63\u78ba\u304b\u3064\u52b9\u679c\u7684\u306b\u69cb\u7bc9\u3059\u308b\u305f\u3081\u306e\u5f37\u529b\u306a\u30c4\u30fc\u30eb\u3068\u3057\u3066\u5229\u7528\u3067\u304d\u308b\u3068\u8003\u3048\u3089\u308c\u308b\u3002 Angewandte Chemie International Edition, 2023, e20230946. DOI: 10.1002\/anie.202309469","rel":"","context":"In "News"","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2088,"url":"https:\/\/supraceramics.jp\/en\/2025\/07\/2088\/","url_meta":{"origin":1886,"position":1},"title":"Publication | Angew. Chem. Int. Ed. (Minato, Sadakane et al.) \u201cA Structure-Preserving, Dimensionality-Increasing Strategy for the Stepwise Synthesis of Microporous \u03b1-MoO3 with a Broad (100) Surface\u201d","author":"shorike","date":"2025\u5e747\u67082\u65e5","format":false,"excerpt":"A Structure-Preserving, Dimensionality-Increasing Strategy for the Stepwise Synthesis of Microporous \u03b1-MoO3 with a Broad (100) Surface Takuo Minato*, Misato Miyamoto, Satoshi Ishikawa, Norihito Hiyoshi, Makoto Maeda, Kenji Komaguchi, Masahiro Sadakane Metal oxides with diverse structures and dimensionalities are typically synthesized via solid-state or hydrothermal reactions. However, it is quite difficult\u2026","rel":"","context":"In "News"","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":825,"url":"https:\/\/supraceramics.jp\/2023\/12\/825\/","url_meta":{"origin":1886,"position":2},"title":"The 2nd Symposium on Materials Chemistry for New Properties and Functions","author":"shorike","date":"2023\u5e7412\u67084\u65e5","format":false,"excerpt":"The 2nd Symposium on Materials Chemistry for New Properties and Functions Ookayama Main building 3F Room 345 (\u7b2c2 \u4f1a\u8b70\u5ba4), Tokyo Institute of Technology 5 December, 2023 Program: 10:40 Opening (Kazuhiko Maeda, Tokyo Tech) 10:45 (Oxy)nitrides\/carbides: materials of choice for catalysis (Franck Tessier, Rennes U.) 11:30 From Chemical Solution Processes to\u2026","rel":"","context":"In "Event"","block_context":{"text":"Event","link":"https:\/\/supraceramics.jp\/en\/category\/event\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":1216,"url":"https:\/\/supraceramics.jp\/2022\/12\/1216\/","url_meta":{"origin":1886,"position":3},"title":"The 1st Symposium on Materials Chemistry for New Properties and Functions","author":"shorike","date":"2022\u5e7412\u670811\u65e5","format":false,"excerpt":"The 2nd Symposium on Materials Chemistry for New Properties and Functions Ookayama Main building 3F Room 345 (\u7b2c2 \u4f1a\u8b70\u5ba4), Tokyo Institute of Technology 5 December, 2022 Program: 9:30 Opening (Kazuhiko Maeda, Tokyo Tech) 9:35 Development of Sustainable and Safe Synthesis Method of Metal Oxynitrides Using Solid-Nitriding Agents (Kiyofumi Katagiri, Hiroshima\u2026","rel":"","context":"In "Event"","block_context":{"text":"Event","link":"https:\/\/supraceramics.jp\/en\/category\/event\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":534,"url":"https:\/\/supraceramics.jp\/2023\/01\/534\/","url_meta":{"origin":1886,"position":4},"title":"Publication | ACS Catal. (Maeda, et al.) “Selective CO\u2082-to-Formate Conversion Driven by Visible Light over a Precious-Metal-Free Nonporous Coordination Polymer”","author":"shorike","date":"2023\u5e741\u670810\u65e5","format":false,"excerpt":"Selective CO\u2082-to-Formate Conversion Driven by Visible Light over a Precious-Metal-Free Nonporous Coordination Polymer Yoshinobu Kamakura, Shuhei Yasuda, Naoki Hosokawa, Shunta Nishioka, Sawa Hongo, Toshiyuki Yokoi, Daisuke Tanaka*, Kazuhiko Maeda* Metal\u2013organic frameworks (MOFs) and coordination polymers (CPs) are potential candidates for high-performance photocatalysts because of their high tunability of electronic and\u2026","rel":"","context":"In "News"","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":1899,"url":"https:\/\/supraceramics.jp\/en\/2023\/01\/1899\/","url_meta":{"origin":1886,"position":5},"title":"Publication | ACS Catal. (Maeda, et al.) “Selective CO\u2082-to-Formate Conversion Driven by Visible Light over a Precious-Metal-Free Nonporous Coordination Polymer”","author":"shorike","date":"2023\u5e741\u670810\u65e5","format":false,"excerpt":"Selective CO\u2082-to-Formate Conversion Driven by Visible Light over a Precious-Metal-Free Nonporous Coordination Polymer Yoshinobu Kamakura, Shuhei Yasuda, Naoki Hosokawa, Shunta Nishioka, Sawa Hongo, Toshiyuki Yokoi, Daisuke Tanaka*, Kazuhiko Maeda* Metal\u2013organic frameworks (MOFs) and coordination polymers (CPs) are potential candidates for high-performance photocatalysts because of their high tunability of electronic and\u2026","rel":"","context":"In "News"","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]}],"_links":{"self":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts\/1886","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/users\/222414606"}],"replies":[{"embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/comments?post=1886"}],"version-history":[{"count":1,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts\/1886\/revisions"}],"predecessor-version":[{"id":1887,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts\/1886\/revisions\/1887"}],"wp:attachment":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/media?parent=1886"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/categories?post=1886"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/tags?post=1886"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}