{"id":2026,"date":"2025-05-12T16:14:30","date_gmt":"2025-05-12T07:14:30","guid":{"rendered":"https:\/\/supraceramics.jp\/?p=2026"},"modified":"2025-05-12T16:14:30","modified_gmt":"2025-05-12T07:14:30","slug":"publication-j-mater-chem-c-kusumoto-shimabukuro-ogiwara-fukui-tsuji-et-al-flexible-organic-inorganic-hybrid-crystals-of-tiniv-chloride-and-naphthalenediimide-exploring-elastici","status":"publish","type":"post","link":"https:\/\/supraceramics.jp\/en\/2025\/05\/2026\/","title":{"rendered":"Publication | J. Mater. Chem. C (Kusumoto, Shimabukuro, Ogiwara, Fukui, Tsuji et al.) \u201cFlexible Organic-Inorganic Hybrid Crystals of Tin(IV) Chloride and Naphthalenediimide: Exploring Elasticity, Mechanochromism, and Photothermal Conversion\u201d"},"content":{"rendered":"<p>Flexible Organic-Inorganic Hybrid Crystals of Tin(IV) Chloride and Naphthalenediimide <\/p>\n<p>S. Kusumoto, S. Masuda, R. Suzuki, M. Tachibana, M. Shimabukuro, M. Kobayashi, N. Ogiwara, S. Uchida, T. Fukui, Y. Tsuji, M. Okamura, S. Hikichi, Y. Kim, Y. Koide<\/p>\n<p>Organic\u2013inorganic hybrid metal halides (OIMHs) are emerging functional materials with diverse applications. However, the exploration of mechanically soft OIMHs remains limited. This study introduces tin(IV) OIMH crystals (1 and 1w), incorporating a naphthalenediimide (NDI)-based organic cation (3pmNDI), which exhibit elastic flexibility, mechanochromism, and photothermal conversion. The unique one-dimensional (1D) slip-stacked assembly of 3pmNDI cations, influenced by the presence or absence of lattice water (1wvs.1), dictates their mechanical properties and chromic behavior. Compound 1 exhibits an exceptionally low elastic modulus (Er = 1.84 \u00b1 0.21 GPa), as measured by nanoindentation, and a photothermal conversion efficiency of 63%. These findings showcase the potential of OIMHs as multifunctional flexible crystals.<\/p>\n<p><\/a><br \/>\n<a href=\" https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2025\/tc\/d5tc00891c\"><br \/>\n<em>J. Mater. Chem. C<\/em>, 13, 8470-8478 (2025). (DOI: 10.1039\/D5TC00891C)<br \/>\n<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Flexible Organic-Inorganic Hybrid Crystals of Tin(IV) Chloride and Naphthalenediimide S. Kusumoto, S. Masuda, R. Suzuki, M. Tachibana, M. Shimabukuro, M. Kobayashi, N. Ogiwara, S. Uchida, T. Fukui, Y. Tsuji, M. Okamura, S. Hikichi, Y. Kim, Y. Koide Organic\u2013inorganic hybrid metal halides (OIMHs) are emerging functional materials with diverse applications. However, the exploration of mechanically soft [&hellip;]<\/p>\n","protected":false},"author":222414606,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"advanced_seo_description":"","jetpack_seo_html_title":"","jetpack_seo_noindex":false,"_themeisle_gutenberg_block_has_review":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_locale":"en_US","_original_post":"https:\/\/supraceramics.jp\/?p=2024","_jetpack_feature_clip_id":0,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2},"jetpack_post_was_ever_published":false},"categories":[124830],"tags":[],"class_list":["post-2026","post","type-post","status-publish","format-standard","hentry","category-news","en-US"],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"","jetpack_likes_enabled":true,"jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/pe2JgX-wG","jetpack-related-posts":[{"id":2024,"url":"https:\/\/supraceramics.jp\/2025\/05\/2024\/","url_meta":{"origin":2026,"position":0},"title":"Publication | J. Mater. Chem. C (Kusumoto, Shimabukuro, Ogiwara, Fukui, Tsuji et al.) \u201cFlexible Organic-Inorganic Hybrid Crystals of Tin(IV) Chloride and Naphthalenediimide: Exploring Elasticity, Mechanochromism, and Photothermal Conversion\u201d","author":"shorike","date":"2025\u5e745\u670812\u65e5","format":false,"excerpt":"\u5171\u540c\u7814\u7a76\u6210\u679c\uff1a\u6709\u6a5f\u7121\u6a5f\u30cf\u30a4\u30d6\u30ea\u30c3\u30c9\u5f3e\u6027\u7d50\u6676\u306e\u5275\u88fd\u3068\u30e1\u30ab\u30ce\u30af\u30ed\u30df\u30ba\u30e0\u53ca\u3073\u5149\u71b1\u5909\u63db\u7279\u6027\uff08A03\u6960\u672c\u3001C03\u5cf6\u888b\u3001C03 \u837b\u539f\u3001A03\u798f\u4e95\u3001B02 \u8fbb\uff09 Flexible Organic-Inorganic Hybrid Crystals of Tin(IV) Chloride and Naphthalenediimide S. Kusumoto, S. Masuda, R. Suzuki, M. Tachibana, M. Shimabukuro, M. Kobayashi, N. Ogiwara, S. Uchida, T. Fukui, Y. Tsuji, M. Okamura, S. Hikichi, Y. Kim, Y. Koide \u672c\u7814\u7a76\u3067\u306f\u3001\u5f3e\u6027\u7684\u306b\u67d4\u8edf\u306a\u5909\u5f62\u304c\u53ef\u80fd\u306a\u6709\u6a5f\u2013\u7121\u6a5f\u30cf\u30a4\u30d6\u30ea\u30c3\u30c9\u30e1\u30bf\u30eb\u30cf\u30e9\u30a4\u30c9\u7d50\u6676\uff08OIMHs\uff09\u306e\u5275\u88fd\u306b\u6210\u529f\u3057\u307e\u3057\u305f\u3002\u4e00\u822c\u306b\u3001OIMH\u7d50\u6676\u3067\u306f\u3001\u6709\u6a5f\u30ab\u30c1\u30aa\u30f3\u3068\u91d1\u5c5e\u30cf\u30e9\u30a4\u30c9\u3068\u306e\u9593\u306b\u6bd4\u8f03\u7684\u5f37\u3044\u30af\u30fc\u30ed\u30f3\u76f8\u4e92\u4f5c\u7528\u304c\u50cd\u304f\u305f\u3081\u3001\u5916\u90e8\u304b\u3089\u306e\u5fdc\u529b\u306b\u5bfe\u3057\u3066\u8106\u5f31\u3067\u3059\u3002\u3057\u304b\u3057\u3001\u672c\u7814\u7a76\u3067\u306f\u3001\u7d50\u6676\u5185\u306b\u4e00\u6b21\u5143\u7684\u306a\u03c0\u30b9\u30bf\u30c3\u30ad\u30f3\u30b0\u69cb\u9020\u3092\u5c0e\u5165\u3059\u308b\u3053\u3068\u3067\u3001\u6a5f\u68b0\u7684\u306b\u67d4\u8edf\u306aOIMH\u7d50\u6676\u306e\u5275\u88fd\u3092\u5b9f\u73fe\u3057\u307e\u3057\u305f\u3002\u3055\u3089\u306b\u3001\u3053\u306e\u5bc6\u306a\u30b9\u30bf\u30c3\u30ad\u30f3\u30b0\u69cb\u9020\u306b\u8d77\u56e0\u3059\u308b\u30e1\u30ab\u30ce\u30af\u30ed\u30df\u30ba\u30e0\u3084\u3001\u512a\u308c\u305f\u30e9\u30b8\u30ab\u30eb\u5b89\u5b9a\u6027\u306b\u7531\u6765\u3059\u308b\u9ad8\u3044\u5149\u71b1\u5909\u63db\u6a5f\u80fd\u3082\u78ba\u8a8d\u3055\u308c\u307e\u3057\u305f\u3002\u672c\u6210\u679c\u306f\u3001\u6a5f\u68b0\u7684\u306b\u67d4\u8edf\u306a\u8d85\u30bb\u30e9\u30df\u30c3\u30af\u30b9\u6750\u6599\u958b\u767a\u5411\u3051\u305f\u6709\u76ca\u306a\u77e5\u898b\u3092\u63d0\u4f9b\u3059\u308b\u3082\u306e\u3067\u3059\u3002 J. Mater. Chem. C, 13, 8470-8478 (2025). (DOI: 10.1039\/D5TC00891C)","rel":"","context":"In &quot;News&quot;","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2238,"url":"https:\/\/supraceramics.jp\/en\/2025\/12\/2238\/","url_meta":{"origin":2026,"position":1},"title":"Symposium in Pacifichem 2025, 12\/17 (Wed)","author":"shorike","date":"2025\u5e7412\u67083\u65e5","format":false,"excerpt":"Pacifichem 2025 ~Inorganic Materials with Multiple Components for Energy and Environmental Applications\uff08ING016\uff09~ 12\/17 (Wed), 2025 Hilton Hawaiian Village Organizers: Ryo Ohtani, Jeongsuk Seo, Lianzhou Wang,\u00a0Kazuhiko Maeda \u00a0 Program: 8:00\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 ~Opening Remarks~ 8:05\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Solution Chemistry Engineering for Efficient Kesterite Solar Cells and Modules Xin, Hao (Nanjing University of Posts and Telecommunications)\u2026","rel":"","context":"In &quot;News&quot;","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2232,"url":"https:\/\/supraceramics.jp\/2025\/12\/2232\/","url_meta":{"origin":2026,"position":2},"title":"Symposium in Pacifichem 2025, 12\/17 (Wed)","author":"shorike","date":"2025\u5e7412\u67083\u65e5","format":false,"excerpt":"Pacifichem 2025 ~Inorganic Materials with Multiple Components for Energy and Environmental Applications\uff08ING016\uff09~ 12\/17 (Wed), 2025 Hilton Hawaiian Village Organizers: Ryo Ohtani, Jeongsuk Seo, Lianzhou Wang,\u00a0Kazuhiko Maeda \u00a0 Program: 8:00\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 ~Opening Remarks~ 8:05\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Solution Chemistry Engineering for Efficient Kesterite Solar Cells and Modules Xin, Hao (Nanjing University of Posts and Telecommunications)\u2026","rel":"","context":"In &quot;News&quot;","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":825,"url":"https:\/\/supraceramics.jp\/2023\/12\/825\/","url_meta":{"origin":2026,"position":3},"title":"The 2nd Symposium on Materials Chemistry for New Properties and Functions","author":"shorike","date":"2023\u5e7412\u67084\u65e5","format":false,"excerpt":"The 2nd Symposium on Materials Chemistry for New Properties and Functions Ookayama Main building 3F Room 345 (\u7b2c2 \u4f1a\u8b70\u5ba4), Tokyo Institute of Technology 5 December, 2023 Program: 10:40 Opening (Kazuhiko Maeda, Tokyo Tech) 10:45 (Oxy)nitrides\/carbides: materials of choice for catalysis (Franck Tessier, Rennes U.) 11:30 From Chemical Solution Processes to\u2026","rel":"","context":"In &quot;Event&quot;","block_context":{"text":"Event","link":"https:\/\/supraceramics.jp\/en\/category\/event\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":1907,"url":"https:\/\/supraceramics.jp\/en\/2025\/01\/1907\/","url_meta":{"origin":2026,"position":4},"title":"Publication | J. Mater. Chem. C (Kusumoto, Shimabukuro, Fukui, et al.) \u201cPhotochromism and Efficient Photothermal Conversion of B\u2190N Lewis Adducts Induced by Intramolecular Electron Transfer\u201d","author":"shorike","date":"2025\u5e741\u670810\u65e5","format":false,"excerpt":"Efficient Photothermal Conversion of B\u2190N Lewis Adducts Kusumoto, T. Mio, K. Rakumitsu, M. Shimabukuro, M. Kobayashi, T. Fukui, N. Hamamoto, T. Ishizaki, Y. Kim, Y. Koide The unique potential of B \u2190 N Lewis adducts, a series of compounds composed of triphenylborane and pyridine\/pyrazine derivatives, was investigated, which exhibited both\u2026","rel":"","context":"In &quot;News&quot;","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2110,"url":"https:\/\/supraceramics.jp\/en\/2025\/07\/2110\/","url_meta":{"origin":2026,"position":5},"title":"Publication | Chem. Commun. (Kusumoto, Tsuji et al.) \u201cFerromagnetic and Plastically Deformable Organic-Inorganic Hybrid Crystal: (C\u2087H\u2089NH\u2083)\u2082CuCl\u2084\u201d","author":"shorike","date":"2025\u5e747\u670829\u65e5","format":false,"excerpt":"Ferromagnetic and Plastically Deformable Organic-Inorganic Hybrid Crystal: (C\u2087H\u2089NH\u2083)\u2082CuCl\u2084 S. Kusumoto, S. Nagasawa, R. Suzuki, M. Tachibana, Y. Tsuji, H. Zenno, Y. Nakashima, S. Hayami, Y. Kim, Y. Koide We report a plastically deformable organic\u2013inorganic hybrid crystal, (C7H9NH3)2CuCl4, exhibiting ferromagnetism below 8 K. Its 2D layered structure enables stress-induced plastic bending\u2026","rel":"","context":"In &quot;News&quot;","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]}],"_links":{"self":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts\/2026","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/users\/222414606"}],"replies":[{"embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/comments?post=2026"}],"version-history":[{"count":1,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts\/2026\/revisions"}],"predecessor-version":[{"id":2027,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts\/2026\/revisions\/2027"}],"wp:attachment":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/media?parent=2026"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/categories?post=2026"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/tags?post=2026"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}