{"id":2088,"date":"2025-07-02T14:36:25","date_gmt":"2025-07-02T05:36:25","guid":{"rendered":"https:\/\/supraceramics.jp\/?p=2088"},"modified":"2025-07-02T14:36:25","modified_gmt":"2025-07-02T05:36:25","slug":"publication-angew-chem-int-ed-minato-sadakane-et-al-a-structure-preserving-dimensionality-increasing-strategy-for-the-stepwise-synthesis-of-microporous-%ef%81%a1-moo3-with-a-broad","status":"publish","type":"post","link":"https:\/\/supraceramics.jp\/en\/2025\/07\/2088\/","title":{"rendered":"Publication | Angew. Chem. Int. Ed. (Minato, Sadakane et al.) \u201cA Structure-Preserving, Dimensionality-Increasing Strategy for the Stepwise Synthesis of Microporous \u03b1-MoO3 with a Broad (100) Surface\u201d"},"content":{"rendered":"<p>A Structure-Preserving, Dimensionality-Increasing Strategy for the Stepwise Synthesis of Microporous \u03b1-MoO3 with a Broad (100) Surface<\/p>\n<p>Takuo Minato*, Misato Miyamoto, Satoshi Ishikawa, Norihito Hiyoshi, Makoto Maeda, Kenji Komaguchi, Masahiro Sadakane<\/p>\n<p>Metal oxides with diverse structures and dimensionalities are typically synthesized via solid-state or hydrothermal reactions. However, it is quite difficult to retain the structures of the starting materials when 0D metal salts or molecular clusters are used as precursors because higher-dimensional structures form by structural reorganization through isomerization and decomposition\/condensation reactions. In this study, we demonstrated a structure-preserving, dimensionality-increasing strategy for the synthesis of 2D \u03b1-MoO3 from 0D [Mo2O5(H2O)6]2+ species via a 1D [Mo2O6{(CH3)2NCHO}]n intermediate while maintaining the structures of the precursors. By simple temperature-controlled calcination, metastable crystals of \u03b1-MoO3 in which the (100) plane was the broad face were successfully synthesized, differing from conventional \u03b1-MoO3 in which the (010) plane is the broad face. In addition, the prepared metastable crystals possessed large surface areas, unusual micropores, and surface-exposed coordinatively unsaturated Mo sites, allowing them to serve as high-performance acid catalysts. This synthesis strategy is expected to facilitate the synthesis of metastable structures and the design of defects and surface structures at the atomic level.<\/p>\n<p><a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202506758\"><br \/>\n<em>Angew. Chem. Int. Ed.<\/em>, e202506758 (2025). (DOI: 10.1002\/anie.202506758)<br \/>\n<\/a><br \/>\nSelected as a Hot Paper<\/p>\n","protected":false},"excerpt":{"rendered":"<p>A Structure-Preserving, Dimensionality-Increasing Strategy for the Stepwise Synthesis of Microporous \u03b1-MoO3 with a Broad (100) Surface Takuo Minato*, Misato Miyamoto, Satoshi Ishikawa, Norihito Hiyoshi, Makoto Maeda, Kenji Komaguchi, Masahiro Sadakane Metal oxides with diverse structures and dimensionalities are typically synthesized via solid-state or hydrothermal reactions. However, it is quite difficult to retain the structures of [&hellip;]<\/p>\n","protected":false},"author":222414606,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"advanced_seo_description":"","jetpack_seo_html_title":"","jetpack_seo_noindex":false,"_themeisle_gutenberg_block_has_review":false,"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_locale":"en_US","_original_post":"https:\/\/supraceramics.jp\/?p=2085","_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2}},"categories":[124830],"tags":[],"class_list":["post-2088","post","type-post","status-publish","format-standard","hentry","category-news","en-US"],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"","jetpack_likes_enabled":true,"jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/pe2JgX-xG","jetpack-related-posts":[{"id":2085,"url":"https:\/\/supraceramics.jp\/2025\/07\/2085\/","url_meta":{"origin":2088,"position":0},"title":"Publication | Angew. Chem. Int. Ed. (Minato, Sadakane et al.) \u201cA Structure-Preserving, Dimensionality-Increasing Strategy for the Stepwise Synthesis of Microporous \u03b1-MoO3 with a Broad (100) Surface\u201d","author":"shorike","date":"2025\u5e747\u67082\u65e5","format":false,"excerpt":"\u7814\u7a76\u6210\u679c\uff1a\u524d\u99c6\u4f53\u69cb\u9020\u3092\u4fdd\u6301\u3057\u305f\u307e\u307e\u69cb\u9020\u306e\u6b21\u5143\u6027\u3092\u9010\u6b21\u7684\u306b\u5897\u52a0\u3055\u305b\u308b\u5408\u6210\u624b\u6cd5\u306b\u3088\u308a(100)\u9762\u304c\u4e3b\u306a\u9762\u3068\u306a\u308b\u9178\u5316\u30e2\u30ea\u30d6\u30c7\u30f3\u3092\u5408\u6210\uff08A02\u5b9a\u91d1\uff09 A Structure-Preserving, Dimensionality-Increasing Strategy for the Stepwise Synthesis of Microporous \uf061-MoO3 with a Broad (100) Surface Takuo Minato*, Misato Miyamoto, Satoshi Ishikawa, Norihito Hiyoshi, Makoto Maeda, Kenji Komaguchi, Masahiro Sadakane \u672c\u7814\u7a76\u3067\u306f\u3001\u524d\u99c6\u4f53\u69cb\u9020\u3092\u4fdd\u6301\u3057\u305f\u307e\u307e0\u6b21\u5143\u306e\u5206\u5b50\u3092\u7e4b\u3052\u30661\u6b21\u5143\u68d2\u72b6\u69cb\u9020\u3092\u4f5c\u308a\u3001\u68d2\u3092\u4e26\u3079\u30662\u6b21\u5143\u30b7\u30fc\u30c8\u72b6\u9178\u5316\u7269\u3092\u4f5c\u308b\u3001\u3068\u3044\u3046\u65b0\u3057\u3044\u9178\u5316\u7269\u9010\u6b21\u5408\u6210\u6cd5\u306e\u958b\u767a\u306b\u6210\u529f\u3057\u307e\u3057\u305f\u3002\u5408\u6210\u4e2d\u9593\u4f53\u3067\u3042\u308bMo2O6(C3H7NO)\u306f\u6709\u6a5f\u5c0f\u5206\u5b50\u306e\u914d\u4f4d\u306b\u3088\u308a2\u6b21\u5143\u30b7\u30fc\u30c8\u3078\u306e\u7e2e\u5408\u3092\u6291\u5236\u3057\u305f1\u6b21\u5143\u8d85\u30bb\u30e9\u30df\u30c3\u30af\u30b9\u3068\u307f\u306a\u3059\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002\u672c\u7814\u7a76\u3067\u5f97\u3089\u308c\u305f2\u6b21\u5143\u30b7\u30fc\u30c8\u72b6\u9178\u5316\u7269\u03b1-MoO3\u306f\u5f93\u6765\u306e\u03b1-MoO3\u3068\u306f\u7570\u306a\u308a\u53cd\u5fdc\u6027\u306e\u9ad8\u3044(100)\u9762\u304c\u591a\u304f\u9732\u51fa\u3057\u3066\u3044\u305f\u307b\u304b\u3001\u30df\u30af\u30ed\u5b54\u3084\u5927\u304d\u306a\u6bd4\u8868\u9762\u7a4d\u3092\u6709\u3057\u3001\u9178\u89e6\u5a92\u3068\u3057\u3066\u9ad8\u3044\u6d3b\u6027\u3092\u793a\u3059\u3053\u3068\u3082\u660e\u3089\u304b\u306b\u3057\u307e\u3057\u305f\u3002\u672c\u7814\u7a76\u3067\u63d0\u6848\u3057\u305f\u5408\u6210\u6226\u7565\u3092\u69d8\u3005\u306a\u9178\u5316\u7269\u5408\u6210\u306b\u5fdc\u7528\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u3001\u9ad8\u6027\u80fd\u30fb\u9ad8\u6a5f\u80fd\u306a\u89e6\u5a92\u6750\u6599\u3084\u96fb\u6975\u6750\u6599\u306e\u5275\u88fd\u304c\u53ef\u80fd\u306b\u306a\u308b\u3068\u671f\u5f85\u3055\u308c\u307e\u3059\u3002 Angew. Chem. Int. Ed., e202506758 (2025). (DOI: 10.1002\/anie.202506758) Selected as a Hot Paper \u30d7\u30ec\u30b9\u30ea\u30ea\u30fc\u30b9 (\u5e83\u5cf6\u5927\u5b66)","rel":"","context":"In &quot;News&quot;","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":1886,"url":"https:\/\/supraceramics.jp\/en\/2023\/07\/1886\/","url_meta":{"origin":2088,"position":1},"title":"Publication | Angew. Chem. Int. Ed. (Minato, Sadakane) \u201cA Cationic Metal Glue Strategy for Expanding Paramagnetic Hetero-Multinuclear Metal\u2013Oxo Clusters within Polyoxometalate Ligands\u201d","author":"shorike","date":"2023\u5e747\u670829\u65e5","format":false,"excerpt":"A Cationic Metal Glue Strategy for Expanding Paramagnetic Hetero-Multinuclear Metal\u2013Oxo Clusters within Polyoxometalate Ligands Takuo Minato, Masahiro Sadakane Precise structural design of large hetero-multinuclear metal-oxo clusters is crucial for controlling their large spin ground states and multielectron redox properties for application as a single-molecule magnet (SMM), molecular magnetic refrigeration, and\u2026","rel":"","context":"In &quot;News&quot;","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2238,"url":"https:\/\/supraceramics.jp\/en\/2025\/12\/2238\/","url_meta":{"origin":2088,"position":2},"title":"Symposium in Pacifichem 2025, 12\/17 (Wed)","author":"shorike","date":"2025\u5e7412\u67083\u65e5","format":false,"excerpt":"Pacifichem 2025 ~Inorganic Materials with Multiple Components for Energy and Environmental Applications\uff08ING016\uff09~ 12\/17 (Wed), 2025 Hilton Hawaiian Village Organizers: Ryo Ohtani, Jeongsuk Seo, Lianzhou Wang,\u00a0Kazuhiko Maeda \u00a0 Program: 8:00\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 ~Opening Remarks~ 8:05\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Solution Chemistry Engineering for Efficient Kesterite Solar Cells and Modules Xin, Hao (Nanjing University of Posts and Telecommunications)\u2026","rel":"","context":"In &quot;News&quot;","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2232,"url":"https:\/\/supraceramics.jp\/2025\/12\/2232\/","url_meta":{"origin":2088,"position":3},"title":"Symposium in Pacifichem 2025, 12\/17 (Wed)","author":"shorike","date":"2025\u5e7412\u67083\u65e5","format":false,"excerpt":"Pacifichem 2025 ~Inorganic Materials with Multiple Components for Energy and Environmental Applications\uff08ING016\uff09~ 12\/17 (Wed), 2025 Hilton Hawaiian Village Organizers: Ryo Ohtani, Jeongsuk Seo, Lianzhou Wang,\u00a0Kazuhiko Maeda \u00a0 Program: 8:00\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 ~Opening Remarks~ 8:05\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 Solution Chemistry Engineering for Efficient Kesterite Solar Cells and Modules Xin, Hao (Nanjing University of Posts and Telecommunications)\u2026","rel":"","context":"In &quot;News&quot;","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2276,"url":"https:\/\/supraceramics.jp\/en\/2026\/01\/2276\/","url_meta":{"origin":2088,"position":4},"title":"Publication | Chem. Mater. (Tsuji, Tanaka, Maeda et al.) \u201cSubstituent-Position-Dependent Electrochemical CO2 Reduction Activity of Pb\u2013S-Based Coordination Polymers\u201d","author":"shorike","date":"2026\u5e741\u670819\u65e5","format":false,"excerpt":"Substituent-Position-Dependent Electrochemical CO2 Reduction Activity of Pb\u2013S-Based Coordination Polymers Shunta Iwamoto, Ryohei Akiyoshi, Sora Nakasone, Chomponoot Suppaso, Megumi Okazaki, Kazuhide Kamiya, Yuta Tsuji,* Daisuke Tanaka,* Kazuhiko Maeda* Developing electrocatalysts for CO2 reduction is essential for the effective use of renewable energy. Materials containing molecules such as coordination polymers have strong\u2026","rel":"","context":"In &quot;News&quot;","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2280,"url":"https:\/\/supraceramics.jp\/en\/2026\/01\/2280\/","url_meta":{"origin":2088,"position":5},"title":"Publication | J. Am. Chem. Soc. (Ohmi, Taniguchi, Bhawna, Fukui, Yamamoto et al.) \u201cDimensionality Reduction of Formamidinium-Rich Lead Iodide Perovskite-Derived Structures\u201d","author":"shorike","date":"2026\u5e741\u670819\u65e5","format":false,"excerpt":"Dimensionality Reduction of Formamidinium-Rich Lead Iodide Perovskite-Derived Structures Takuya Ohmi, Wataru Taniguchi, Bhawna, Tomoya Fukui, Yuki Haruta, Takayuki Nakanishi, Takanori Fukushima, Makhsud I. Saidaminov, Masaki Azuma, Takafumi Yamamoto* Formamidinium lead iodide, FAPbI3 (FA+ = CH(NH2)2+), with a cubic perovskite structure is among the most studied organic\u2013inorganic hybrid perovskites. Despite several\u2026","rel":"","context":"In &quot;News&quot;","block_context":{"text":"News","link":"https:\/\/supraceramics.jp\/en\/category\/news\/"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]}],"_links":{"self":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts\/2088","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/users\/222414606"}],"replies":[{"embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/comments?post=2088"}],"version-history":[{"count":1,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts\/2088\/revisions"}],"predecessor-version":[{"id":2091,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/posts\/2088\/revisions\/2091"}],"wp:attachment":[{"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/media?parent=2088"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/categories?post=2088"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/supraceramics.jp\/wp-json\/wp\/v2\/tags?post=2088"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}